30. Angelina Jolie – 3

Angelina Jolie has had a few very high-profile marriages. Her first marriage was to actor Jonny Lee Miller from 1996 to 1999. She then married Billy Bob Thornton in 2000, and they were divorced in 2003. Most recently she married Brad Pitt in one of the most high-profile marriages ever in 2014, and they divorced in 2016.